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Convolution Differentiation
 
Convolution differentiation is a method of suppressing broad underlying spectral lines in order to emphasize narrower spectral lines. Strong smoothing of the spectrum (e.g., by severe negative exponential weighting of the time data) will suppress the narrow lines but minimally affect very broad ones; subtracting such a smoothed spectrum from the original will largely remove the contributions from the broad lines. This provides a means of baseline correction.
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New acceleration techniques will :
reduce scan times 
cause artifacts 
increase expenses 
be useful if you have a lot of experience 
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