Paramagnetic materials attract and repel like normal magnets when subject to a
magnetic field. This
alignment of the atomic
dipoles with the
magnetic field tends to strengthen it, and is described by a relative magnetic
permeability greater than unity. Paramagnetism requires that the atoms individually have permanent
dipole moments even without an applied
field, which typically implies a partially filled electron shell. In pure Paramagnetism (without an external
magnetic field), these atomic
dipoles do not interact with one another and are randomly oriented in the absence of an external
field, resulting in zero net moment.
Paramagnetic materials in magnetic
fields will act like magnets but when the
field is removed, thermal motion will quickly disrupt the magnetic
alignment. In general, paramagnetic effects are small (
magnetic susceptibility of the order of 10
-3 to 10
-5).
In
MRI,
gadolinium (Gd) one of these paramagnetic materials is used as a
contrast agent. Through interactions between the electron spins of the paramagnetic
gadolinium and the water nuclei nearby, the
relaxation rates (T1 and T2) of the water protons are increased (T1 and T2 times are decreased), causing an increase in signal on
T1 weighted images.
See also
contrast agents,
magnetism,
ferromagnetism,
superparamagnetism, and
diamagnetism.